By Jose Luis Serrano
Examine on metal-containing liquid crystals is a speedily increasing, multidisciplinary box with new fabrics continuously being synthesized and novel purposes being built. 'Metallomesogens' is the 1st entire survey of the sphere, introducing the reader to:
* fabrics design
* synthesis
* actual properties
* rising applications
Carefully chosen references around off this well-organized compendium. it truly is an quintessential advisor to skilled researchers in coordination and organometallic chemistry in addition to in liquid-crystal and fabrics technology. beginners and graduate scholars also will take advantage of this didactically sound creation to the sphere
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Extra resources for Metallomesogens: Synthesis, Properties, and Applications
Example text
Liq. Cryst. 1985, 123, 369-375. M. C. Marchon, D. Guillon, A. Skoulios, J. Phys. Lett. M. Giroud-Godquin, J. C. Marchon, D. Guillon, A. Skoulios, J. Phys. Chem. 1986,90,5502- 5503; c) J. C. Marchon, P. Maldivi, A. M. Giroud-Godquin, D. Guillon, A. Skoulios. P. Strommen, Phil. Trans. R. SOC. Lond. A 1990, 330, 109- 116. [28] M. Ibn-Elhaj, D. Guillon, A. M. Giroud-Godquin, J. C. Marchon, J. Phys. II France 1992, 2, 21 97 - 2206. [29] N. Usoltseva, K. Praefcke, D. Singer, B. Gundogan, Liq. Cryst. 1994, 16, 601 -616.
Adapted from Ref. 28. bromo, iodo, thiocyanato or azide bridges (Fig. 2-19) have been reported to form lyotropic mesophases in apolar solvents such as heptane, pentadecane, or eicosane [29]. At high concentrations of the chloro-bridged complex a mesophase similar to the thermotropic discotic oblique columnar phase (DobJ is observed. Once again, addition of paraffinic solvents to the systems decreases the lateral interaction between the columns, leading to the formation of less ordered mesophases.
1994, 16, 601-616. [25] a) P. Espinet, J. Perez, M. B. Ros, J. L. Serrano, J. Barbera, A. M. Levelut, Organometallics 1990, 9, 2028-2033; b) P. Espinet, J. Etxebarria, M. Marcos, J. PerCz, A. Remon, J. L. Serrano, Angew. Chem. Znt. Ed. Eng. 1989, 28, 1065- 1066. [26] K. Ohta, N. Akimoto, 0. Tekienaka, T. Fujimoto, I. Yamamoto, J. Mater. Chem. 1994, 4, 61 -49. [27] a) J. Barbera, P. Espinet, E. Lalinde, M. L. Cryst. 1987, 2, 833 - 842; b) D. Singer, A. Liebmann, K. Praefcke, J. H. Wendorff, Liq.
