By G.V. Avvakumov, Mamoru Senna, N. V. Kosova
Mechanical equipment of the activation of chemical procedures are at the moment universal for the synthesis of assorted compounds. The current monograph offers with the improvement of a singular method of mechanochemical synthesis in response to reactions of strong acids, bases, hydrated compounds, crystal hydrates, simple and acidic salts. This procedure has been referred to as gentle mechanochemical synthesis.
The monograph contains the papers released via the current authors. They describe the result of their investigations n the final a long time. New theoretical and experimental information on kinetics and mechanism of soppy mechanochemical reactions within the combos of compounds pointed out above to provide advanced oxide compounds are provided. the outline of recent excessive vigorous and excessive effective turbines delivering powerful prevalence of those reactions is added. the chances of using smooth mechanochemical synthesis for fabrics utilized in catalysts, fabric technological know-how, electronics, etc., are mentioned. some great benefits of the strategy proposed compared to different tools are validated.
The monograph is designed for researchers, engineers and technicians engaged in chemical and ceramic undefined, for scientists and scholars really expert within the sector of improvement, and alertness of recent fabrics.
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Extra resources for Soft Mechanochemical Synthesis: A Basis for New Chemical Technologies
Sample text
Sulphates and Their Solutions. Leningrad: Nauka, 1980. Chapter 3. 1. Thermodynamics of acid-base reactions Chemical interaction between solids involves the consumption of some compounds and the formation of others. These processes occur in agreement with physicochemical laws and can be characterized using the fundamental thermodynamic equations. The main of them is the equation which describes the changes of the isobar-isothermal potential (Gibbs free energy) with the process enthalpy and entropy the functions of the state.
Ed. P. In 10 volumes. Moskva: VINITI, 1970-1985. 32. Chalii V. P. Hydroxides of Metals. Kiev: Naukova Dumka, 1972. 33. Dzisko, Vera and Karnaukhov, Anatolii and Tarasova, Djemma. Physico-Chemical Basis of Synthesis of Oxide Catalysts. Novosibirsk: Nauka, 1978. 34. W. Nuclear magnetic resoance studies of the hydrolisis and polimerisation of the hexa-aquo-aluminium (III) cation. J. Chem. Soc. Dalton Trans. 1972; 5: 604-9. 35. Iohanson G. The crystal structures of and Acta Chem. Scand. 1962; 16: 103-20.
The crystal structures of and Acta Chem. Scand. 1962; 16: 103-20. 36. A. About formation mechanism of colloidal particles. Uspekhi Chimii, 1955; 24: 249-59. 37. , Vischnyakova G. P. Formation of aluminium hydroxide at aqing. Kinetika i Kataliz, 1976; 17: 483-90. 38. I. et al. About the role of polymerization and depolymerization of silicic acid in the processes of formation and rearrangement of the gel carcass. In Adsorption and Adsorbents. Kiev: Naukova Dumka, 1972. 39. G. Hydrated Oxides of the Elements of IV and V groups.
