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Inorganic and organometallic polymers by Ronald D. Archer

By Ronald D. Archer

A balanced and concise insurance of inorganic polymers

Inorganic polymers include components except carbon as a part of their significant spine constitution and are recognized to show quite a lot of composition and constitution. Emphasizing actual homes, chemical synthesis, and characterization of inorganic polymers, Inorganic and Organometallic Polymers provides worthy and informative assurance of the field.

With a variety of examples of real-world functional functions and end-of-chapter workouts, Inorganic and Organometallic Polymers is acceptable to be used as a textual content in designated issues in natural and polymer chemistry classes. The booklet beneficial properties worthy sections on:

  • Classification schemes for inorganic polymers
  • Synthesis of inorganic polymers, together with step-growth syntheses, chain polymerizations, ring-opening polymerizations, and reductive coupling reactions
  • Practical inorganic polymer chemistry issues comparable to polymer elastomers, dental and clinical polymers, lubricants, lithographic resists, pre-ceramics, and more

Inorganic and Organometallic Polymers is a worthy one-volume creation for pro and scholar inorganic chemists, polymer chemists, and fabrics scientists.

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R. in Encyclopedia of Polymer Science and Engineering; Kroschwitz, J. , Mark, H. , Bikales, N. , Overberger, C. G. , John Wiley and Sons: NY, 1987; Vol. 10, pp 541–594. 16. Sheats, J. , Carraher, C. , Pittman, C. , Culbertson, B. M. in Metal-Containing Polymeric Materials; Pittman, C. , Carraher, C. , Sheats, J. E. and Culbertson, B. , Plenum Press: NY, 1996, pp 3–37. 17. , Manners, I. Chem. Rev. 1999, 99, 1515. 18. Mark, J. E. , H. , West, R. in Inorganic Polymers; Mark, J. , Allcock, H. R. , Prentice Hall: Englewood Cliffs, NJ, 1992, pp 61–140.

Amorphous behavior and hydrophilicity vs. hydrophobicity) can be introduced into the polyphosphazenes through substituent variations. This leads to a wide variety of potential uses. The cost of the polymers has limited their practicality, but the innocuous nature of their hydrolysis products in biological systems provides impetus for biomedical uses of these polymers where cost is less important than effectiveness and lack of toxicity. Early attempts to commercialize the polyphosphazenes were economically unsuccessful, but new ventures are underway as this book is being written — not too surprising given their potential as elastomers, solid polymer electrolytes, hydrogels, microencapsulators, bioerodibles, adhesives, liquid crystalline polymers, nonlinear optical materials, and fire-resistant materials.

Note that carboxylate bridges can be with the carbonyl either on the cyclopentadiene ring (Fig. 23d) or on the bridging group (Fig. 23e). Polyamide linkages on the cyclopentadienyl ring or in a ˇ-position of an alkyl group on the ring are stable (Fig. 23f,g), whereas ˇ-substituents are unstable. Note the R bridges can be either alkyl or aryl (Fig. 23g), and polyureas and 24 INORGANIC POLYMERS AND CLASSIFICATION SCHEMES polycarboxylates can also be obtained with ˇ-substituents(Fig. 23h,i). A boron derivative (Fig.

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