By Ernest L. Eliel
content material: methods for uneven synthesis as directed towards typical items / Barry M. Trost --
man made regulate resulting in usual items / Teruaki Mukaiyama --
uneven synthesis of chiral tertiary alcohols in excessive enantiomeric extra / Ernest L. Eliel, Jorma okay. Koskimies, Bruno Lohri, W. Jack Frazee, Susan Morris-Natschke, Joseph E. Lynch, and Kenso Soai --
Acyclic stereoselection through the aldol condensation / Clayton H. Heathcock --
uneven carbon-carbon bond forming reactions through chiral chelated intermediates : diastereoselective uneven synthesis of 1,2-disubstituted cycloalkanecarboxaldehydes / Kenji Koga --
uneven carbon-carbon bond forming reactions through chiral oxazolines / Albert I. Meyers --
hugely selective synthesis with novel metal reagents / Hitosi Nozaki, Tamejiro Hiyama, Koichiro Oshima, and Kazuhiko Takai --
Novel methods to the uneven synthesis of peptides / Iwao Ojima --
uneven carbon-carbon bond formation utilizing enantiomerically natural vinylic sulfoxides / Gary H. Posner, John P. Mallamo, Kyo Miura, and Martin Hulce --
uneven reactions : a problem to the economic chemist / Gabriel Saucy and Noal Cohen --
Stereochemistry of heterogeneous uneven catalytic hydrogenation / Kaoru Harada --
uneven Grignard cross-coupling catalyzed through chiral phosphine-nickel and phosphine-palladium complexes / Tamio Hayashi --
Rhodium(I) catalyzed enantioselective hydrogen migration of prochiral allylamines / ok. Tani, T. Yamagata, S. Otsuka, S. Akutagawa, H. Kumobayashi, T. Taketomi, H. Takaya, A. Miyashita, and R. Noyori --
software of immobilized enzymes for uneven reactions / Ichiro Chibata --
uneven synthesis utilizing cofactor-requiring enzymes / George M. Whitesides, Chi-Huey Wong, and Alfred Pollak --
Mechanistic issues of biomimetic uneven discount rates / Atsuyoshi Ohno --
Stereochemistry of one-carbon move reactions / Heinz G. Floss --
an invaluable and with ease obtainable chiral desk bound part for the liquid chromatographic separation of enantiomers / William H. Pirkle, John M. Finn, Bruce C. bog down, James Schreiner, and James R. Pribish --
New uneven reactions utilizing (S)-2-aminomethylpyrrolidine derivatives / Masatoshi Asami --
Liquid chromatographic answer of enantiomeric [alpha]-amino acid derivatives making use of a chiral diamide section / Shoji Hara, Akira Dobashi, and Masakatzu Eguchi --
uneven relief with chiral NADH version compounds / Yuzo Inouye --
uneven hydrogenation of cyclic dipeptides containing [alpha], [beta]-dehydroamino acid residues and next coaching of optically natural [alpha]-amino acids / Nobuo Izumiya.
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Extra info for Asymmetric Reactions and Processes in Chemistry
1972, 382. 19. -i. Bull. 1975, 23, 527. 20. J. Chem. 1979, 44, 3598. 21. E. Tetrahedron Lett. 1981, 22, 2855. 22. L. unpublished observations. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. 3. ELIEL ET AL. ch003 23. 24. 25. 26. L. unpublished observations. ; Soai, K. Tetrahedron Lett. 1981, 22, 2859. W. Chem. 1971, 36, 3553. ; Konno, K. (London) 1964, 233. 27. Regarding previous reports on chiral 10a and 10b, cf. J. Chem. H. Soc. 1951, 73, 2391. 28. ; Asami, M. Lett. 1978, 1253; 1979, 705.
1981, 1109. RECEIVEDDecember 21, 1981. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. 3 Asymmetric Synthesis of Chiral Tertiary Alcohols in High Enantiomeric Excess ERNEST L . ELIEL, JORMA K. KOSKIMIES, BRUNO LOHRI, W. JACK FRAZEE, SUSAN MORRIS-NATSCHKE, JOSEPH E . ch003 University of North Carolina, Department of Chemistry, Chapel Hill, NC 27514 Chiral 1,3-oxathianes have been used as adjuvants for highly stereoselective asymmetric syntheses. Acylation (direct or via an intermediate carbinol) proceeds to give exclusively equatorial products in which the chirality has been transferred to C(2) of the 1,3-oxathiane.
1980, 163. ; Takeda, T. ibid. 1979, 1207. ; Takeda, T. ibid, 1980, 635. ; Iwasawa, N. ibid. 1979, 697. ; Narasaka, K. ibid. 1979, 1117. ; Iwasawa, N. ibid. 1981, 29. ; Iwasawa, N. ibid. 1981, 913. ; Mukaiyama, T. ibid. 1979, 1279. ; Mukaiyama, T. ibid. 1981, 1005. ; Mukaiyama, T. ibid. 1981, 1109. RECEIVEDDecember 21, 1981. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. 3 Asymmetric Synthesis of Chiral Tertiary Alcohols in High Enantiomeric Excess ERNEST L . ELIEL, JORMA K.